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52755-34-7

Benzene, 1-chloro-4-[(1-methyl-1-nitroethyl)thio]- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 52755-34-7 Structure

  • Basic information

    1. Product Name: Benzene, 1-chloro-4-[(1-methyl-1-nitroethyl)thio]-
    2. Synonyms:
    3. CAS NO:52755-34-7
    4. Molecular Formula: C9H10ClNO2S
    5. Molecular Weight: 231.703
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 52755-34-7.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Benzene, 1-chloro-4-[(1-methyl-1-nitroethyl)thio]-(CAS DataBase Reference)
    10. NIST Chemistry Reference: Benzene, 1-chloro-4-[(1-methyl-1-nitroethyl)thio]-(52755-34-7)
    11. EPA Substance Registry System: Benzene, 1-chloro-4-[(1-methyl-1-nitroethyl)thio]-(52755-34-7)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 52755-34-7(Hazardous Substances Data)

52755-34-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 52755-34-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,2,7,5 and 5 respectively; the second part has 2 digits, 3 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 52755-34:
(7*5)+(6*2)+(5*7)+(4*5)+(3*5)+(2*3)+(1*4)=127
127 % 10 = 7
So 52755-34-7 is a valid CAS Registry Number.

52755-34-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-methyl-1-nitroethyl p-chlorophenyl sulphide

1.2 Other means of identification

Product number -
Other names p-chlorophenyl 1-methyl-1-nitroethyl sulphide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:52755-34-7 SDS

52755-34-7Relevant articles and documents

Radical-nucleophilic substitution (SRN1) reactions. Part 7. Reactions of aliphatic α-substituted nitro compounds

Al-Khalil,Bowman,Gaitonde,Marley,Richardson

, p. 1557 - 1565 (2007/10/03)

α-Nitrothiocyanates R2C(SCN)NO2 have been prepared by oxidative addition of thiocyanate anion to nitronate anions and undergo SRN1 substitution reactions by loss of thiocyanate with nitronate anions, phenylsulfinate, azide and p-nitro- and p-chloro-benzenethiolates in dipolar aprotic solvents. 2-Nitro-2-thiocyanatopropane and other 2-substituted-2-nitropropanes [Me2C(X)NO2 with X = I, Br, Cl, NO2, PhSO2] react with thiolates by SRN1 reactions and/or redox reactions to give disulfides by a polar abstraction or chain SET (SET2) mechanisms. The products are dependent on the nucleophilicity of the thiolates, the polarisability of the α-substituent, the solvent and the presence of light catalysis, radical traps or strong electron acceptors. 2-Substituted-2-nitropropanes [Me2C(X)NO2 with X = N3, NO2, CN, p-NO2-C6H4-N=N] undergo SRN1 substitutions with thiolates by loss of nitrite. 2-Substituted-2-nitropropanes Me2C(X)NO2 and thiolates only yield disulfides in methanol due to solvation of the nitro groups.

Radical-Nucleophilic Substitution (SRN1) Reactions. Part 2. Preparation and Reactions of α-Nitrosulphides

Bowman, W. Russell,Rakshit, Devajvoti,Valmas, Michael D.

, p. 2327 - 2336 (2007/10/02)

A range of α-nitrosulphides have been prepared by oxidative addition of thiolate anion to the anion of 2-nitropropane, SN2 attack of the anion of 2-nitropropane on symmetrical disulphides, and SRN1 reaction of 2-substituted-2-nitropropanes with thiolate anions.The α-nitrosulphides undergo SRN1 substitution with the anion of 2-nitropropane, and SRN1 substitution or redox reactions with thiolate anions.The electron spin resonance (e.s.r.) spectrum of the radical-anion of 1-methyl-1-nitroethyl pyrimidin-2-yl sulphide has been observed.

EFFECTS OF METHANOL SOLVATION ON THE NUCLEOPHILIC REACTIONS OF THIOLATES WITH 2-SUBSTITUTED-2-NITROPROPANES

Al-Khalil, Suleiman I.,Bowman, W. Russell

, p. 461 - 464 (2007/10/02)

Methanol solvation prevents SRN1 substitution in the reaction of Me2C(X)NO2 with thiolates and favours an alternative redox reaction to yield disulphide and nitronate.

RADICAL-NUCLEOPHILIC SUBSTITUTION (SRN1) REACTIONS OF α-NITRO-THIOCYANATES

Al-Khalil, Suleiman I.,Bowman, W. Russell

, p. 2517 - 2520 (2007/10/02)

α-Nitro-thiocyanates undergo substitution by a SRN1 mechanism with a range of anions to give loss of thiocyanate, corroborating behaviour observed for the intermediate α-nitro-thiocyanato radical-anions by e.s.r. spectroscopy.

REACTIONS OF THIOLATE ANIONS WITH 2-SUBSTITUTED-2-NITROPROPANES

Bowman, W. Russel,Richardson, Geoffrey D.

, p. 1551 - 1554 (2007/10/02)

Thiolates undergo substitution reactions with 2-substituted-2-nitropropanes by an SRN1 mechanism or are oxidised to disulphides by an ionic mechanism.

Radical-Nucleophilic Substitution (SRN1) Reactions: Preparation and Reactions of α-Nitrosulphides

Bowman, W. Russell,Richardson, Geoffrey D.

, p. 1407 - 1413 (2007/10/02)

α-Nitrosulphides were prepared by SRN1 reaction of 2-bromo-2-nitropropane with thiolate anions, and by SN2 attack of sodium 2-nitropropan-2-ide on symmetrical disulphides.The α-nitrosulphides undergo radical-nucleophilic substitution (SRN1) by nitronate, sulphinate, and malonate anions, but not by thiolate anions.

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