First, label everything:

simulate this circuit – Schematic created using CircuitLab
Ensure that all resistor voltages are labelled in accordance with passive sign convention. That is, the positive sign goes at the end where current enters the resistor. This isn't strictly necessary, but doing otherwise will likely lead to confusion with signs later on.
There are only 4 nodes where current branches, so called "branch nodes", labelled A, B, C and D. These are where you must apply KCL:
$$
\begin{aligned}
I_4 - I_8 - I_2 &= 0 \\ \\
I_8 + I_5 - I_4 &= 0 \\ \\
I_2 - I_1 - I_3 &= 0 \\ \\
I_1 + I_3 - I_5 &= 0 \\ \\
\end{aligned}
$$
There are three loops, and these are where we apply KVL. I will go clockwise around all three. As I go around a loop, for each element that I traverse I will add voltage when that traversal incurs a rise in potential, and I will subtract whenever I encounter a fall in potential, in keeping with my annotated voltage polarities:
$$
\begin{aligned}
+V_8 - V_1 &= 0 \\ \\
+V_1 - V_2 - V_3 - V_5 &= 0 \\ \\
+V_3 -V_4 - V_7 - V_6 &= 0 \\ \\
\end{aligned}
$$
Usually we can combine Ohm's law and KVL into a single step, but I will separate them here, and combine them in a moment. This is Ohm's law applied to all the resistors:
$$
\begin{aligned}
V_8 &= I_8R_1 \\ \\
V_2 &= I_2R_2 \\ \\
V_3 &= I_3R_3 \\ \\
V_5 &= I_5R_5 \\ \\
V_4 &= I_1R_4 \\ \\
V_6 &= I_1R_6 \\ \\
\end{aligned}
$$
Plugging these voltages into the KVL equations will reduce them all (with the exception of \$V_7\$) to be in terms of currents \$I_X\$, something that we would usually already have done while writing those KVL equations:
$$
\begin{aligned}
I_8R_1 - V_1 &= 0 \\ \\
1 - I_2R_2 - I_3R_3 - I_5R_5 &= 0 \\ \\
I_3R_3 - I_1R_4 - V_7 - I_1R_6 &= 0 \\ \\
\end{aligned}
$$
These are all the simultaneous equations collated, that we must solve:
$$
\begin{aligned}
I_4 - I_8 - I_2 &= 0 \\ \\
I_8 + I_5 - I_4 &= 0 \\ \\
I_2 - I_1 - I_3 &= 0 \\ \\
I_1 + I_3 - I_5 &= 0 \\ \\
I_8R_1 - V_1 &= 0 \\ \\
1 - I_2R_2 - I_3R_3 - I_5R_5 &= 0 \\ \\
I_3R_3 - I_1R_4 - V_7 - I_1R_6 &= 0 \\ \\
\end{aligned}
$$
While these equations form a complete description of the state of the circuit, and you can solve them to find all unknowns, there are a couple of interesting points to note.
A quick check will show that there are six unknown quantities, \$I_4\$, \$I_8\$, \$I_2\$, \$I_5\$, \$I_3\$ and \$V_7\$, but seven equations. The extra one is due to \$I_2=I_5\$, which can be deduced intuitively, if we encase the entire right side in a "black box":

simulate this circuit
With nowhere else for current to enter or leave that dotted box, by KCL it's already clear that current entering must equal current leaving via the only two paths available, thus \$I_2=I_5\$.
Another observation is that current \$I_8\$ can be evaluated immediately:
$$
\begin{aligned}
I_8R_1 - V_1 &= 0 \\ \\
I_8 &= \frac{V_1}{R_1} \\ \\
&= \frac{1V}{10\Omega} \\ \\
&= 100mA \\ \\
\end{aligned}
$$
A similar situation will arise every time you have an independent voltage source directly across a resistor. In fact, \$I_8\$ could be disregarded completely, as you will find that it will disappear from the equations as you try to solve them. Even with R1 removed, the following will yield exactly the same results for the remaining currents and potentials:

simulate this circuit